DEGRADATION OF D-RIBONO-1 → 4-LACTONE TO D-ERYTHRONO-1 → 4-LACTONE
نویسندگان
چکیده
منابع مشابه
5-O-Acetyl-d-ribono-1,4-lactone
The title compound, C(7)H(10)O(6), was obtained from a regioselective enzyme-catalysed acyl-ation of d-ribono-1,4-lactone. The five-membered ring of the acyl-ated sugar shows an envelope conformation. In the crystal, the mol-ecules are linked by inter-molecular O-H⋯O hydrogen-bonds, forming a one-dimensional polymeric structure parallel to [010]. In addition, packing analysis shows stacking alo...
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Detached bean (Phaseolus vulgaris) and strawberry (Fragaria) fruits fed l-gulono-1,4-lactone or l-galactono-1,4-lactone convert this compound, in part, to l-ascorbic acid. When l-galactono-1,4-lactone is given as a 0.25% solution to detached bean shoots, the ascorbic acid content is tripled in less than 10 hours. l-Gulono-1,4-lactone is only 5 to 10% as effective as its epimer. Experiments with...
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specification of emotion and appraisal to be used within the framework Elisabeth André, DFKI Yasmine Arafa, ICSTM Luís Botelho, ADETTI Monika Farukuoye, ÖFAI Pedro Figueiredo, ADETTI Patrick Gebhard, DFKI Kristina Höök, SICS Thomas Kulessa, GMD Carlos Martinho, INESC Ana Paiva, INESC Paolo Petta, ÖFAI Pedro Ramos, ADETTI Phoebe Sengers, GMD Alexander Staller, ÖFAI Marco Vala, INESC Abstract: Th...
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In the title compound, C15H16O6, obtained from the acyl-ation reaction between 2,3-O-iso-propyl-idene-d-ribono-1,4-lactone and benzoyl chloride, the known absolute configuration for the lactone moiety of the ester substituent has been confirmed. The five-membered rings of the bicyclic lactone-dioxolane moiety both show envelope conformations and form a dihedral angle of 19.82 (7)° between the l...
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The crystal structure of the title compound, C(13)H(14)O(5), establishes (i) the (S) - rather than (R) - configuration at the acetal carbon and (ii) that both the acetal and the lactone form five- rather than six-membered rings; the absolute configuration is determined by the use of 2-C-methyl-d-ribono-1,4-lactone as the starting material. The compound consists of hydrogen-bonded chains of mol-...
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ژورنال
عنوان ژورنال: Canadian Journal of Chemistry
سال: 1963
ISSN: 0008-4042,1480-3291
DOI: 10.1139/v63-034